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arXiv · 0706.2067

Use of detailed kinetic mechanisms for the prediction of autoignitions

Frédéric Buda·Pierre-Alexandre Glaude·Frédérique Battin-Leclerc·Richard Porter·Kevin J. Hughes·John F. Griffiths
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Abstract

This paper describes how automatically generated detailed kinetic mechanisms are obtained for the oxidation of alkanes and how these models could lead to a better understanding of autoignition and cool flame risks at elevated conditions. Examples of prediction of the occurrence of different autoignition phenomena, such as cool flames or two-stage ignitions are presented depending on the condition of pressure, temperature and mixture composition. Three compounds are treated, a light alkane, propane, and two heavier ones, n-heptane and n-decane.

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Frédéric Buda, Pierre-Alexandre Glaude, Frédérique Battin-Leclerc, Richard Porter, Kevin J. Hughes, John F. Griffiths. 2007-06-14. Use of detailed kinetic mechanisms for the prediction of autoignitions. https://arxiv.org/abs/0706.2067

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