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arXiv · 0708.3437

Anomalous dispersion of optical phonons at the neutral-ionic transition: Evidence from diffuse X-ray scattering

Gabriele D'Avino·Alberto Girlando·Anna Painelli·Marie-Hélène Lemée-Cailleau·Zoltán G. Soos
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Abstract

Diffuse X-ray data for mixed stack organic charge-transfer crystals approaching the neutral-ionic phase transition can be quantitatively explained as due to the softening of the optical phonon branch. The interpretation is fully consistent with vibrational spectra, and underlines the importance of electron-phonon coupling in low-dimensional systems with delocalized electrons.

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Gabriele D'Avino, Alberto Girlando, Anna Painelli, Marie-Hélène Lemée-Cailleau, Zoltán G. Soos. 2007-08-25. Anomalous dispersion of optical phonons at the neutral-ionic transition: Evidence from diffuse X-ray scattering. https://doi.org/10.1103/physrevlett.99.156407

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