Correlation between the energy shell structure and geometry in metallic nanoclusters: quasi-resonance states, isotope effect

Vladimir Kresin

doi:10.1063/1.2841469

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arXiv · 0804.0466

Correlation between the energy shell structure and geometry in metallic nanoclusters: quasi-resonance states, isotope effect

Vladimir Kresin

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Abstract

Metallic nanoclusters displaying electronic shell structure exhibit the special feature of a correlation between their geometry and the number of delocalized electrons . Their shape evolution can be described as a quantum oscillation between quasi-resonant states (prolate and oblate configurations) whose amplitudes depend upon the degree of shell filling. The picture explains the evolution of absorption spectra and predicts a peculiar isotope effect .

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Vladimir Kresin. 2008-04-03. Correlation between the energy shell structure and geometry in metallic nanoclusters: quasi-resonance states, isotope effect. https://doi.org/10.1063/1.2841469

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