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arXiv · 0810.0123

Anomalous behavior of the Debye temperature in Fe-rich Fe-Cr alloys

B. F. O. Costa·J. Cieslak·S. M. Dubiel
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Abstract

Debye temperature, $Θ_D$, of Fe-rich Fe$_{100-x}$Cr$_x$ disordered alloys with $0\le x \le 22.3$ was determined from the temperature dependence of the central shift of Mössbauer spectra recorded in the temperature range of 60 -- 300 K. Its compositional dependence shows a maximum at $x \approx 5$ with a relative increase of $\sim 30$% compared to a pure iron. The composition at which the effect occurs correlates well with that at which several other quantities, e. g. the Curie temperature and the spin-wave stiffness coefficient, $D_0$, show their maxima, but the enhancement of $Θ_D$ is significantly greater and comparable with the enhancement of the hyperfine field (spin-density of itinerant $s$-like electrons) in the studied system. The results suggest that the electron-phonon interaction is important in this alloy system.

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B. F. O. Costa, J. Cieslak, S. M. Dubiel. 2008-10-01. Anomalous behavior of the Debye temperature in Fe-rich Fe-Cr alloys. https://doi.org/10.1016/j.jallcom.2009.11.067

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