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arXiv · 0901.1486

Multi-channel modelling of the formation of vibrationally cold polar KRb molecules

Svetlana Kotochigova·Eite Tiesinga·Paul S. Julienne
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Abstract

We describe the theoretical advances that influenced the experimental creation of vibrationally and translationally cold polar $^{40}$K$^{87}$Rb molecules \cite{nphys08,science08}. Cold molecules were created from very-weakly bound molecules formed by magnetic field sweeps near a Feshbach resonance in collisions of ultra-cold $^{40}$K and $^{87}$Rb atoms. Our analysis include the multi-channel bound-state calculations of the hyperfine and Zeeman mixed X$^1Σ^+$ and a$^3Σ^+$ vibrational levels. We find excellent agreement with the hyperfine structure observed in experimental data. In addition, we studied the spin-orbit mixing in the intermediate state of the Raman transition. This allowed us to investigate its effect on the vibrationally-averaged transition dipole moment to the lowest ro-vibrational level of the X$^1Σ^+$ state. Finally, we obtained an estimate of the polarizability of the initial and final ro-vibrational states of the Raman transition near frequencies relevant for optical trapping of the molecules.

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Svetlana Kotochigova, Eite Tiesinga, Paul S. Julienne. 2009-01-12. Multi-channel modelling of the formation of vibrationally cold polar KRb molecules. https://doi.org/10.1088/1367-2630%2F11%2F5%2F055043

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