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arXiv · 0906.1354

Investigation of the role of Ag in Pr$_{1-x}$Ag$_x$MnO$_3$ manganites

Hossein Ahmadvand·Hadi Salamati·Parviz Kameli
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Abstract

X-Ray diffraction, ac susceptibility and electrical resistivity measurements were performed in order to investigate the effect of Ag substitution for Pr in the polycrystalline Pr$_{1-x}$Ag$_x$MnO$_3$ (0.0$\leq$x$\leq$0.25) manganites. The XRD results show that the samples crystallize in the O'-orthorhombic structure with a cooperative Jahn-Teller deformation. We give evidence that the Ag$^{+}$ is not substituted at the Pr$^{3+}$ site in the PrMnO$_{3}$ structure. The increase of $T_{C}$ up to 130 K is suggested to be due to further oxidation of manganite grains by the oxygen released from the metallic silver at high temperatures. No metal-insulator transition was observed in the samples.

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Hossein Ahmadvand, Hadi Salamati, Parviz Kameli. 2009-08-27. Investigation of the role of Ag in Pr$_{1-x}$Ag$_x$MnO$_3$ manganites. https://arxiv.org/abs/0906.1354

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