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arXiv · 0908.0896

Vibrational interference of Raman and high-harmonic generation pathways

Zachary B. Walters·Stefano Tonzani·Chris H. Greene
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Abstract

Experiments have shown that the internal vibrational state of a molecule can affect the intensity of high harmonic light generated from that molecule. This paper presents a model which explains this modulation in terms of interference between different vibrational states occurring during the high harmonic process. In addition, a semiclassical model of the continuum electron propagation is developed which connects with rigorous treatments of the electron-ion scattering.

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Zachary B. Walters, Stefano Tonzani, Chris H. Greene. 2009-08-06. Vibrational interference of Raman and high-harmonic generation pathways. https://doi.org/10.1016/j.chemphys.2009.09.022

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