Observation of the Accelerated Diffusion in Nanoparticles of Paradibromobenzene /Paradihlorbenzene Solid Solution

M. A. Korshunov

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arXiv · 0910.3707

Observation of the Accelerated Diffusion in Nanoparticles of Paradibromobenzene /Paradihlorbenzene Solid Solution

M. A. Korshunov

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Abstract

P-dibromobenzene nanoparticles in a case of paradihlorbenzol molecules have been synthesized. Raman spectrums of these nanoparticles are measured. At diffusion of molecules of paradihlorbenzol in a pdibromobenzene nanoparticle solid solution formed. Modifications in structure of nanoparticles at diffusion are reflected in Raman spectrums. Unlike a solid solution single crystal, in nanoparticles the accelerated diffusion, $D = 1.3 \pm 0.02 10^{-11} cm^2/s$, is observed at room temperature. Calculations show that the accelerated diffusion is caused by magnification of parametres of a lattice at reduction of sizes of nanoparticles.

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M. A. Korshunov. 2009-10-19. Observation of the Accelerated Diffusion in Nanoparticles of Paradibromobenzene /Paradihlorbenzene Solid Solution. https://arxiv.org/abs/0910.3707

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