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arXiv · 1002.3781

Entropy, diffusivity and the energy landscape of a water-like fluid

Alan Barros de Oliveira·Evy A. Salcedo Torres·Charusita Chakravarty·Marcia C. Barbosa
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Abstract

Molecular dynamics simulations and instantaneous normal mode (INM) analysis of a fluid with core-softened pair interactions and water-like liquid-state anomalies are performed to obtain an understanding of the relationship between thermodynamics, transport properties and the poten- tial energy landscape. Rosenfeld-scaling of diffusivities with the thermodynamic excess and pair correlation entropy is demonstrated for this model. The INM spectra are shown to carry infor- mation about the dynamical consequences of the interplay between length scales characteristic of anomalous fluids, such as bimodality of the real and imaginary branches of the frequency distribu- tion. The INM spectral information is used to partition the liquid entropy into two contributions associated with the real and imaginary frequency modes; only the entropy contribution from the imaginary branch captures the non-monotonic behaviour of the excess entropy and diffusivity in the anomalous regime of the fluid.

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Alan Barros de Oliveira, Evy A. Salcedo Torres, Charusita Chakravarty, Marcia C. Barbosa. 2010-02-19. Entropy, diffusivity and the energy landscape of a water-like fluid. https://doi.org/10.1063/1.3429254

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