Nonequilibrium free energy, H theorem and self-sustained oscillations for Boltzmann-BGK descriptions of semiconductor superlattices

Abstract

Semiconductor superlattices (SL) may be described by a Boltzmann-Poisson kinetic equation with a Bhatnagar-Gross-Krook (BGK) collision term which preserves charge, but not momentum or energy. Under appropriate boundary and voltage bias conditions, these equations exhibit time-periodic oscillations of the current caused by repeated nucleation and motion of charge dipole waves. Despite this clear nonequilibrium behavior, if we `close' the system by attaching insulated contacts to the superlattice and keeping its voltage bias to zero volts, we can prove the H theorem, namely that a free energy $Φ(t)$ of the kinetic equations is a Lyapunov functional ($Φ\geq 0$, $dΦ/dt\leq 0$). Numerical simulations confirm that the free energy decays to its equilibrium value for a closed SL, whereas for an `open' SL under appropriate dc voltage bias and contact conductivity $Φ(t)$ oscillates in time with the same frequency as the current self-sustained oscillations.