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arXiv · 1101.4994

Evidence of a new quantum state of nano-confined water

G. F. Reiter·A. I. Kolesnikov·S. J. Paddison·P. M. Platzman·A. P. Moravsky·M. A. Adams·J. Mayers
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Abstract

Deep Inelastic Neutron Scattering provides a means of directly and accurately measuring the momentum distribution of protons in water, which is determined primarily by the protons ground state wavefunction. We find that in water confined on scales of 20A, this wave function responds to the details of the confinement, corresponds to a strongly anharmonic local potential, shows evidence in some cases of coherent delocalization in double wells, and involves changes in zero point kinetic energy of the protons from -40 to +120 meV difference from that of bulk water at room temperature. This behavior appears to be a generic feature of nanoscale confinement. It is exhibited here in 16A inner diameter carbon nanotubes, two different hydrated proton exchange membranes(PEMs), Nafion 1120 and Dow 858, and has been seen earlier in xerogel and 14A diameter carbon nanotubes. The proton conductivity in the PEM samples correlates with the degree of coherent delocalization of the proton.

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G. F. Reiter, A. I. Kolesnikov, S. J. Paddison, P. M. Platzman, A. P. Moravsky, M. A. Adams, J. Mayers. 2011-01-26. Evidence of a new quantum state of nano-confined water. https://arxiv.org/abs/1101.4994

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