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arXiv · 1108.4484

Anomalous low-energy phonons in nearly tetragonal BiFeO3 thin films

K. -Y. Choi·S. H. Do·P. Lemmens·D. Wulferding·C. S. Woo·J. H. Lee·K. Chu·C. -H. Yang
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Abstract

We present evidence for a concomitant structural and ferroelectric transformation around $T_S\sim 360$ K in multiferroic BiFeO$_3$/LaAlO$_3$ thin films close to the tetragonal phase. Phonon excitations are investigated by using Raman scattering as a function of temperature. The low-energy phonon modes at 180-260 cm$^{-1}$ related to the FeO$_6$ octahedron tilting show anomalous behaviors upon cooling through $T_S$; (i) a large hardening amounting to 15 cm$^{-1}$, (ii) an increase of intensity by one order of magnitude, and (iii) an appearance of a dozen new modes. In contrast, the high-frequency modes exhibit only weak anomalies. This suggests an intimate coupling of octahedron tilting to ferroelectricity leading to a simultaneous change of structural and ferroelectric properties.

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K. -Y. Choi, S. H. Do, P. Lemmens, D. Wulferding, C. S. Woo, J. H. Lee, K. Chu, C. -H. Yang. 2011-08-23. Anomalous low-energy phonons in nearly tetragonal BiFeO3 thin films. https://doi.org/10.1103/physrevb.84.132408

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