Preparation and Characterization of Metal-free graphitic Carbon Nitride Film Photocathodes for Light-induced Hydrogen Evolution

Florent Yang; Michael Lublow; Steven Orthmann; Christoph Merschjann; Tobias Tyborski; Marin Rusu; Michael Kanis; Arne Thomas; Rosa Arrigo; Michael Haevecker; Thomas Schedel-Niedrig

arXiv · 1202.3266

Preparation and Characterization of Metal-free graphitic Carbon Nitride Film Photocathodes for Light-induced Hydrogen Evolution

Florent Yang·Michael Lublow·Steven Orthmann·Christoph Merschjann·Tobias Tyborski·Marin Rusu·Michael Kanis·Arne Thomas·Rosa Arrigo·Michael Haevecker·Thomas Schedel-Niedrig

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Abstract

Very recently, it has been shown that an abundant material, polymeric carbon nitride, can produce hydrogen from water under visible-light irradiation in the presence of a sacrificial donor [1]. We will present here the preparation and characterization of graphitic carbon nitride (g-C3N4) films on semiconducting substrates by thermal condensation of dicyandiamide precursor under inert gas conditions. Structural and surface morphological studies of the carbon nitride films suggest a high porosity of g-C3N4 thin film consisting of a network of nanocrystallites. Photo-electrochemical investigations show upon cathodic polarization light-induced hydrogen evolution for a wide range of proton concentrations in the aqueous electrolyte. Additionally, Synchrotron radiation based photoelectron spectroscopy has been applied to study the surface/near-surface chemical composition of the utilized g-C3N4 film photocathodes. For the first time it is shown that g-C3N4 films can be successfully applied as photoelectrochemical material for light induced hydrogen evolution. [1]X. Wang, K. Maeda, A. Thomas, K. Takanabe, G. Xin, J. M. Carlsson, K. Domen, M. Antonietti, Nature Mat. 2009, 8, 76-80.

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Florent Yang, Michael Lublow, Steven Orthmann, Christoph Merschjann, Tobias Tyborski, Marin Rusu, Michael Kanis, Arne Thomas, Rosa Arrigo, Michael Haevecker, Thomas Schedel-Niedrig. 2012-02-15. Preparation and Characterization of Metal-free graphitic Carbon Nitride Film Photocathodes for Light-induced Hydrogen Evolution. https://arxiv.org/abs/1202.3266

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