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arXiv · 1204.4331

Compressibility and structural stability of ultra-incompressible bimetallic interstitial carbides and nitrides

D. Errandonea·J. Ruiz-Fuertes·J. A. Sans·D. Santamaria-Perez·O. Gomis·A. Gomez·F. Sapina
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Abstract

We have investigated by means of high-pressure x-ray diffraction the structural stability of Pd2Mo3N, Ni2Mo3C0.52N0.48, Co3Mo3C0.62N0.38, and Fe3Mo3C. We have found that they remain stable in their ambient-pressure cubic phase at least up to 48 GPa. All of them have a bulk modulus larger than 330 GPa, being the least compressible material Fe3Mo3C, B0 = 374(3) GPa. In addition, apparently a reduction of compressibility is detected as the carbon content increased. The equation of state for each material is determined. A comparison with other refractory materials indicates that interstitial nitrides and carbides behave as ultra-incompressible materials.

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D. Errandonea, J. Ruiz-Fuertes, J. A. Sans, D. Santamaria-Perez, O. Gomis, A. Gomez, F. Sapina. 2012-04-19. Compressibility and structural stability of ultra-incompressible bimetallic interstitial carbides and nitrides. https://doi.org/10.1103/physrevb.85.144103

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