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arXiv · 1205.5374

Structural instability of EuTiO3 from X-ray powder diffraction

J. Köhler·R. Dinnebier·A. Bussmann-Holder
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Abstract

We have recently predicted and subsequently verified experimentally by specific heat measurements that EuTiO3 undergoes a structural phase transition at elevated temperature TS = 282 K. The origin of the phase transition has been attributed to the softening of a transverse acoustic mode stemming from an oxygen octahedral rotation analogous to SrTiO3. Here we demonstrate that the theoretical interpretation is correct by using high resolution laboratory X-ray powder diffraction which evidences a cubic to tetragonal phase transition in EuTiO3. The room temperature structure could be refined in with a = 3.9082(2) {\AA} and at 100 K the refinement in the tetragonal space group resulted in a = 5.5192(2) and c = 7.8164(8) {\AA}.

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J. Köhler, R. Dinnebier, A. Bussmann-Holder. 2012-05-24. Structural instability of EuTiO3 from X-ray powder diffraction. https://arxiv.org/abs/1205.5374

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