Identification of the true elastic modulus of high density polyethylene from tensile tests using an appropriate reduced model of the elastoviscoplastic behavior

Abstract

The rheological parameters of materials are determined in the industry according to international standards established generally on the basis of widespread techniques and robust methods of estimation. Concerning solid polymers and the determination of Young's modulus in tensile tests, ISO 527-1 or ASTM D638 standards rely on protocols with poor scientific content: the determination of the slope of conventionally defined straight lines fitted to stress-strain curves in a given range of elongations. This paper describes the approach allowing for a correct measurement of the instantaneous elastic modulus of polymers in a tensile test. It is based on the use of an appropriate reduced model to describe the behavior of the material. The model comes a thermodynamical framework and allows to reproduce the behavior of an HDPE Polymer until large strains, covering the elastoviscoplastic and hardening regimes. Well-established principles of parameter estimation in engineering science are used to found the identification procedure. It will be shown that three parameters only are necessary to model experimental tensile signals: the instantaneous ('Young's') modulus, the maximum relaxation time of a linear distribution (described with a universal shape) and a strain hardening modulus to describe the 'relaxed' state. The paper ends with an assessment of the methodology. Our results of instantaneous modulus measurements are compared with those obtained with other physical experiments operating at different temporal and length scales.