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arXiv · 1207.0962

IrSr_2Sm_{1.15}Ce_{0.85}Cu_{2.175}O_{10}: A Novel Reentrant Spin-Glass Material

R. H. Colman·A. C. Mclaughlin
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Abstract

A new iridium containing layered cuprate material, IrSr_2Sm_{1.15}Ce_{0.85}Cu_{2.175}O_{10, has been synthesized by conventional ambient-pressure solid-state techniques. The material's structure has been fully characterized by Rietveld refinement of high resolution synchrotron X-ray diffraction data; tilts and rotations of the IrO_6 octahedra are observed as a result of a bond mismatch between in-plane Ir-O and Cu-O bond lengths. DC-susceptibility measurements evidence a complex set of magnetic transitions upon cooling that are characteristic of a reentrant spin-glass ground-state. The glassy character of the lowest temperature, Tg=10 K, transition is further confirmed by AC-susceptibility measurements, showing a characteristic frequency dependence that can be well fitted by the Vogel-Fulcher law and yields a value of \Delta_(T_f)/[T_f \Delta log({\omega})] =0.015(1), typical of dilute magnetic systems. Electronic transport measurements show the material to be semiconducting at all temperatures with no transition to a superconducting state. Negative magnetoresistance is observed when the material is cooled below 25 K, and the magnitude of this magnetoresistance is seen to increase upon cooling to a value of MR = -9 % at 8 K.

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R. H. Colman, A. C. Mclaughlin. 2012-07-04. IrSr_2Sm_{1.15}Ce_{0.85}Cu_{2.175}O_{10}: A Novel Reentrant Spin-Glass Material. https://doi.org/10.1103/physrevb.85.144419

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