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arXiv · 1209.3162

A novel crystal polymorph of volborthite, Cu3V2O7(OH)2 2H2O

Hajime Ishikawa·Jun-ichi Yamaura·Yoshihiko Okamoto·Hiroyuki Yoshida·Gøran J. Nilsen·Zenji Hiroi
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Abstract

A new polymorph of volborthite [tricopper(II) divanadium(V) heptaoxide dihydroxide dihydrate], Cu3V2O7(OH)2 2H2O, has been discovered in a single crystal prepared by hydrothermal synthesis. X-ray analysis reveals that the monoclinic structure has the space group C2/c at room temperature, which is different from that of the previously reported C2/m structure. Both structures have Cu3O6(OH)2 layers composed of edge-sharing CuO4(OH)2 octahedra, with V2O7 pillars and water molecules between the layers. The Cu atoms occupy two and three independent crystallographic sites in the C2/m and C2/c structures, respectively, likely giving rise to different magnetic interactions between CuII spins in the kagome lattices embedded in the Cu3O6(OH)2 layers.

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Hajime Ishikawa, Jun-ichi Yamaura, Yoshihiko Okamoto, Hiroyuki Yoshida, Gøran J. Nilsen, Zenji Hiroi. 2012-09-14. A novel crystal polymorph of volborthite, Cu3V2O7(OH)2 2H2O. https://doi.org/10.1107/s010827011202536x

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