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arXiv · 1209.4442

Does Singlet Fission Enhance the Performance of Organic Solar Cells?

K. Aryanpour·J. A. Muñoz·S. Mazumdar
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Abstract

Singlet fission, in which the optical spin-singlet exciton dissociates into two low energy triplet excitons, has been proposed as a viable approach to enhance the quantum efficiency of organic solar cells. We show that even when singlet fission is occurring in the donor molecule, the electronic structure at the donor$-$acceptor interface must satisfy specific requirements for the solar cell performance to be enhanced by this process. We focus on the pentacene$-$C$_{60}$ solar cell, and on the basis of our calculations and available experimental data, we conclude that there is not enough evidence that these requirements are met by the donor$-$acceptor interface here. We propose experiments that can determine whether the minimal requirement for enhanced performance driven by singlet fission is met in this and other solar cells.

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K. Aryanpour, J. A. Muñoz, S. Mazumdar. 2013-03-14. Does Singlet Fission Enhance the Performance of Organic Solar Cells?. https://doi.org/10.1021/jp312302x

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