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arXiv · 1301.2590

Dipolar Radicals in Crossed Electric and Magnetic Fields

John L. Bohn·Goulven Quéméner
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Abstract

Paramagnetic, dipolar Hund's case-a radicals are considered in the presence of arbitrary, non-collinear combinations of electric and magnetic fields. The field-dependent part of the Hamiltonian is found to be exactly diagonalizable, and described by quantum numbers given by the projection of the molecule's total angular momentum along a space-fixed axis that is determined by both the fields and the electric and magnetic dipole moments of the molecule. In cases of strong fields, this procedure identifies a set of quantum numbers for the molecule in crossed fields. We dub this set a "Hund's case-X" basis.

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John L. Bohn, Goulven Quéméner. 2013-01-11. Dipolar Radicals in Crossed Electric and Magnetic Fields. https://doi.org/10.1080/00268976.2013.783721

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