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arXiv · 1303.3694

Synthesis and structure of high-quality films of copper polyphthalocyanine - 2D conductive polymer

Darya M. Sedlovets·Maksim V. Shuvalov·Yury V. Vishnevskiy·Vladimir T. Volkov·Igor I. Khodos·Oleg V. Trofimov·Vitaly I. Korepanov
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Abstract

We propose an experimental approach, by which thin films of copper polyphthalocyanine (CuPPC) can be directly synthesized in a chemical vapor deposition (CVD) set-up at mild temperature (420 {\deg}C). High polymerization degree and high crystallinity of the films was confirmed by TEM, FTIR and UV-VIS studies; the stacking structure of CuPPC layers was determined, inter-layer spacing was estimated from XRD and TEM electron-diffraction. Quantum-chemical study performed providing support for experimental structure determination and yielding information on the electronic structure.

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Darya M. Sedlovets, Maksim V. Shuvalov, Yury V. Vishnevskiy, Vladimir T. Volkov, Igor I. Khodos, Oleg V. Trofimov, Vitaly I. Korepanov. 2013-03-15. Synthesis and structure of high-quality films of copper polyphthalocyanine - 2D conductive polymer. https://doi.org/10.1016/j.materresbull.2013.06.015

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