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arXiv · 1305.1034

Predicting multidimensional distributive properties of hyperbranched polymer resulting from AB2 polymerization with substitution, cyclization and shielding

Ivan Kryven·Piet D. Iedema
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Abstract

A deterministic mathematical model for the polymerization of hyperbranched molecules accounting for substitution, cyclization, and shielding effect has been developed as a system of nonlinear population balances. The solution obtained by a novel approximation method shows perfect agreement with the analytical solution in limiting cases and provides, for the first time in this class of polymerization problems, full multidimensional results.

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Ivan Kryven, Piet D. Iedema. 2013-05-05. Predicting multidimensional distributive properties of hyperbranched polymer resulting from AB2 polymerization with substitution, cyclization and shielding. https://doi.org/10.1016/j.polymer.2013.05.009

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