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arXiv · 1306.1880

Effect of Spin-Orbit Interaction on (4d)^3- and (5d)^3 -Based Transition-Metal Oxides

Hiroyasu Matsuura·Kazumasa Miyake
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Abstract

The effects of a spin-orbit interaction on transition-metal ions of (4d)^3- and (5d)^3 -based oxides in which three electrons occupy t_{2g} orbitals are studied. The amplitude of the magnetic moment of d electrons on the 5d and 4d orbitals is estimated by numerical diagonalization. It is found that the magnetic moment is reduced by the spin-orbit interaction. It is suggested that (4d)^3- and (5d)^3 -based oxides are located in the middle of the L-S and J-J coupling schemes.

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Hiroyasu Matsuura, Kazumasa Miyake. 2013-06-08. Effect of Spin-Orbit Interaction on (4d)^3- and (5d)^3 -Based Transition-Metal Oxides. https://doi.org/10.7566/jpsj.82.073703

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