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arXiv · 1308.1577

Electronic transport properties of indolyl spirooxazine/merooxazine-based light-driven molecular switch: The effect of amino/nitro substituents

H. Zhao·Y. Q. Xu·W. K. Zhao·K. Gao
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Abstract

By applying non-equilibrium Green's function formulation combined with first-principles density functional theory,we explore the electronic transport properties of indolinospironaphthoxazine (SO)/indolinomeronaphthoxazine (MO).The results indicate that the MO allows a far larger current than the SO.The substituent group can cause the shift of the energy levels.Higher ON/OFF current ratio can be obtained if either amino or nitro substituent is placed at the position of naphthalene moiety.Our results suggest that such molecular wires can generally display perfect switching function and the efficiency can be tuned flexibly by adding certain substituent groups to the molecules.

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H. Zhao, Y. Q. Xu, W. K. Zhao, K. Gao. 2013-08-07. Electronic transport properties of indolyl spirooxazine/merooxazine-based light-driven molecular switch: The effect of amino/nitro substituents. https://doi.org/10.1016/j.physb.2013.12.027

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