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arXiv · 1310.8470

A direct comparison of CVD-grown and exfoliated MoS2 using optical spectroscopy

G. Plechinger·J. Mann·E. Preciado·D. Barroso·A. Nguyen·J. Eroms·C. Schüller·L. Bartels·T. Korn
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Abstract

MoS2 is a highly interesting material system, which exhibits a crossover from an indirect band gap in the bulk crystal to a direct gap for single layers. Here, we perform a direct comparison between large-area MoS$_2$ films grown by chemical vapor deposition (CVD) and MoS$_2$ flakes prepared by mechanical exfoliation from natural bulk crystal. Raman spectroscopy measurements show differences between the in-plane and out-of-plane phonon mode positions in CVD-grown and exfoliated MoS$_2$. Photoluminescence (PL) mapping reveals large regions in the CVD-grown films that emit strong PL at room temperature, and low-temperature PL scans demonstrate a large spectral shift of the A exciton emission as a function of position. Polarization-resolved PL measurements under near-resonant excitation conditions show a strong circular polarization of the PL, corresponding to a valley polarization.

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BibTeXRIS

G. Plechinger, J. Mann, E. Preciado, D. Barroso, A. Nguyen, J. Eroms, C. Schüller, L. Bartels, T. Korn. 2013-11-04. A direct comparison of CVD-grown and exfoliated MoS2 using optical spectroscopy. https://doi.org/10.1088/0268-1242%2F29%2F6%2F064008

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