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arXiv · 1311.2682

Crystal growth and characterization of Haldane chain compound Ni(C$_3$H$_{10}$N$_2$)$_2$NO$_2$ClO$_4$

W. Tao·L. M. Chen·X. M. Wang·C. Fan·W. P. Ke·X. G. Liu·Z. Y. Zhao·Q. J. Li·X. F. Sun
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Abstract

The bulk single crystals of $S = 1$ chain compound Ni(C$_3$H$_{10}$N$_2$)$_2$NO$_2$ClO$_4$ are grown by using a slow evaporation method at a constant temperature and a slow cooling method. It is found that the optimum condition of growing large crystals is via slow evaporation at 25 $^\circ$C using 0.015 mol Ni(ClO$_4$)$_2$$\cdot$6H$_2$O, 0.015 mol NaNO$_2$, and 0.03 mol 1,3-propanediamine liquid dissolved into 30 ml aqueous solvent. High-quality crystals with size up to $18 \times 7.5 \times 5$ mm$^3$ are obtained. The single crystals are characterized by measurements of x-ray diffraction, magnetic susceptibility, specific heat and thermal conductivity. The susceptibilities along three crystallographic axes are found to exhibit broad peaks at $\sim 55$ K, and then decrease abruptly to zero at lower temperatures, which is characteristic of a Haldane chain system. The specific heat and the thermal conductivity along the $c$ axis can be attributed to the simple phononic contribution and are analyzed using the Debye approximation.

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W. Tao, L. M. Chen, X. M. Wang, C. Fan, W. P. Ke, X. G. Liu, Z. Y. Zhao, Q. J. Li, X. F. Sun. 2013-11-12. Crystal growth and characterization of Haldane chain compound Ni(C$_3$H$_{10}$N$_2$)$_2$NO$_2$ClO$_4$. https://doi.org/10.1016/j.jcrysgro.2011.05.013

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