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arXiv · 1311.3978

Emergence of Molecular Chirality by Vibrational Raman Scattering

Farhad Taher Ghahramani·Afshin Shafiee
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Abstract

In this study, we apply the monitoring master equation describing decoherence of internal states to an optically active molecule prepared in a coherent superposition of nondegenerate internal states interacting with thermal photons at low temperatures. We use vibrational Raman scattering theory up to the first chiral-sensitive contribution, i.e., the mixed electric-magnetic interaction, to obtain scattering amplitudes in terms of molecular polarizability tensors. The resulting density matrix is used to obtain elastic decoherence rates.

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Farhad Taher Ghahramani, Afshin Shafiee. 2013-11-15. Emergence of Molecular Chirality by Vibrational Raman Scattering. https://doi.org/10.1103/physreva.88.032504

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