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arXiv · 1311.6762

Negative area compressibility in silver(I) tricyanomethanide

Sarah A. Hodgson·Jasper Adamson·Sarah J. Hunt·Matthew J. Cliffe·Andrew B. Cairns·Amber L. Thompson·Matthew G. Tucker·Nicholas P. Funnell·Andrew L. Goodwin
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Abstract

The molecular framework Ag(tcm) (tcm$^-$ = tricyanomethanide) expands continuously in two orthogonal directions under hydrostatic compression. The first of its kind, this negative area compressibility behaviour arises from the flattening of honeycomb-like layers during rapid pressure-driven collapse of the interlayer separation.

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Sarah A. Hodgson, Jasper Adamson, Sarah J. Hunt, Matthew J. Cliffe, Andrew B. Cairns, Amber L. Thompson, Matthew G. Tucker, Nicholas P. Funnell, Andrew L. Goodwin. 2013-11-26. Negative area compressibility in silver(I) tricyanomethanide. https://doi.org/10.1039/c3cc47032f

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