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arXiv · 1402.4270

Structure of one-component polymer brushes: Groundstate considerations

Richard L. C. Vink
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Abstract

A coarse-grained model to describe the lateral structure of a one-component polymer brush is presented. In this model, a single polymer chain is described by just two coordinates, namely the position of the grafted monomer, and the monomer on the non-grafted end. Due to its simplicity, the lateral arrangement of large numbers of structural units, each unit containing hundreds of polymers, can be analyzed. We consider here the corresponding low-energy configurations. Provided the grafting density is large enough, the latter all feature hexagonal order, even when the grafted monomers are distributed randomly.

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Richard L. C. Vink. 2014-02-18. Structure of one-component polymer brushes: Groundstate considerations. https://arxiv.org/abs/1402.4270

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