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arXiv · 1403.0972

Molecular weight dependent bimolecular recombination in organic solar cells

Bronson Philippa·Martin Stolterfoht·Ronald D. White·Marrapan Velusamy·Paul L. Burn·Paul Meredith·Almantas Pivrikas
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Abstract

Charge carrier recombination is studied in operational organic solar cells made from the polymer:fullerene system PCDTBT:PC71BM (poly[N-9"-heptadecanyl-2,7-carbazole-alt-5,5-(4',7'-di-2-thienyl-2',1',3'-benzothiadiazole)] : [6,6]-phenyl-C$_{70}$-butyric acid methyl ester). A newly developed technique High Intensity Resistance dependent PhotoVoltage (HI-RPV) is presented for reliably quantifying the bimolecular recombination coefficient independently of variations in experimental conditions, thereby resolving key limitations of previous experimental approaches. Experiments are performed on solar cells of varying thicknesses and varying polymeric molecular weights. It is shown that solar cells made from low molecular weight PCDTBT exhibit Langevin recombination, whereas suppressed (non-Langevin) recombination is found in solar cells made with high molecular weight PCDTBT.

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Bronson Philippa, Martin Stolterfoht, Ronald D. White, Marrapan Velusamy, Paul L. Burn, Paul Meredith, Almantas Pivrikas. 2014-08-05. Molecular weight dependent bimolecular recombination in organic solar cells. https://doi.org/10.1063/1.4891369

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