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arXiv · 1404.1755

A hybrid vanadium fluoride with structurally isolated S = 1 kagome layers

Farida H. Aidoudi·Lewis J. Downie·Russell E. Morris·Mark de Vries·Philip Lightfoot
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Abstract

A new organically-templated vanadium (III) fluoride, (NH4)2(C2H8N)[V3F12], has been prepared using an ionothermal approach. This compound has a unique layered structure featuring distorted S = 1 kagome planes separated by the cationic species. The compound exhibits magnetic frustration, with a canted antiferromagnetic ground state. On further cooling within the ground state a pronounced change in magnetisation kinetics is observed.

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Farida H. Aidoudi, Lewis J. Downie, Russell E. Morris, Mark de Vries, Philip Lightfoot. 2014-04-07. A hybrid vanadium fluoride with structurally isolated S = 1 kagome layers. https://doi.org/10.1039/c4dt00452c

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