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arXiv · 1405.6259

Direct bandgap silicon quantum dots achieved via electronegative capping

A. N. Poddubny·K. Dohnalová
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Abstract

We propose a novel concept of achieving silicon quantum dots with radiative rates enhanced by more than two orders of magnitude up to the values characteristic for direct band gap semiconductors. Our tight-binding simulations show how the surface engineering can dramatically change the density of confined electrons in real- and $k$-space and give rise to the new conduction band levels in $\Gamma$-valley, thus promoting the direct radiative transitions. The effect may be realized by covering the silicon dots with covalently bonded electronegative ligands, such as alkyl or teflon chains and/or by embedding in highly electronegative medium.

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A. N. Poddubny, K. Dohnalová. 2014-05-24. Direct bandgap silicon quantum dots achieved via electronegative capping. https://doi.org/10.1103/physrevb.90.245439

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