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arXiv · 1406.6881

Naturally self-assembled nickel nanolattice

Jaiveer Singh·Netram Kaurav·Niranjan Prasad Lalla·Gunadhor Singh Okram
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Abstract

This is the first report on the critical nature of nanolattice formability of different particle size (~4-10nm) of monodispersed nickel nanoparticles. They exhibit strikingly hexagonal close-packed (hcp) nanolattices without extra forces, whenever trioctylphosphine is (one of) the surfactant(s). This clearly establishes the unique role of nanolattice formability of trioctylphosphine. The c/a ratios are interestingly identical to those of atomic lattices. An attempt has also been made to explain them based on the balanced attractive and repulsive forces of the surfactant-generated cation-anion pairs on the surface of the nanoparticles. The present findings therefore will provide a far-reaching vista to fabrication of varieties of natural nanolattices and their understanding on applications in a new paradigm.

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Jaiveer Singh, Netram Kaurav, Niranjan Prasad Lalla, Gunadhor Singh Okram. 2014-06-26. Naturally self-assembled nickel nanolattice. https://arxiv.org/abs/1406.6881

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