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arXiv · 1408.5175

Activity-induced phase separation and self-assembly in mixtures of active and passive particles

Joakim Stenhammar·Raphael Wittkowski·Davide Marenduzzo·Michael E. Cates
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Abstract

We investigate the phase behavior and kinetics of a monodisperse mixture of active (\textit{i.e.}, self-propelled) and passive isometric Brownian particles through Brownian dynamics simulations and theory. As in a purely active system, motility of the active component triggers phase separation into a dense and a dilute phase; in the dense phase we further find active-passive segregation, with "rafts" of passive particles in a "sea" of active particles. We find that phase separation from an initially disordered mixture can occur with as little as 15 percent of the particles being active. Finally, we show that a system prepared in a suitable fully segregated initial state reproducibly self-assembles an active "corona" which triggers crystallization of the passive core by initiating a compression wave. Our findings are relevant to the experimental pursuit of directed self-assembly using active particles.

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Joakim Stenhammar, Raphael Wittkowski, Davide Marenduzzo, Michael E. Cates. 2015-01-07. Activity-induced phase separation and self-assembly in mixtures of active and passive particles. https://doi.org/10.1103/physrevlett.114.018301

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