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arXiv · 1410.3275

Ruthenium-Europium configuration in the Eu2Ru2O7 pyrochlore

S. Muñoz Pérez·R. Cobas·J. M. Cadogan·J. Albino Aguiar·S. Streltsov·X. Obradors
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Abstract

The magnetic and electronic properties of Eu2Ru2O7 are discussed in terms of the local ruthenium and europium coordinations, electronic band structure calculations and molecular orbital energy levels. A preliminary electronic structure was calculated within the LDA and LSDA+U approximations. The molecular orbital energy level diagrams have been used to interpret the Eu-Ru ligand spectrum and the ensuing magnetic properties. The orbital hybridizations and bonds are discussed.

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S. Muñoz Pérez, R. Cobas, J. M. Cadogan, J. Albino Aguiar, S. Streltsov, X. Obradors. 2014-10-13. Ruthenium-Europium configuration in the Eu2Ru2O7 pyrochlore. https://doi.org/10.1063/1.4906528

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