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arXiv · 1501.02080

High-precision laser spectroscopy of the CO A$^1Π$ - X$^1Σ^+$ (2,0), (3,0) and (4,0) bands

M. L. Niu·F. Ramirez·E. J. Salumbides·W. Ubachs
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Abstract

High-precision two-photon Doppler-free frequency measurements have been performed on the CO A$^1Π$ - X$^1Σ^+$ fourth-positive system (2,0), (3,0), and (4,0) bands. Absolute frequencies of forty-three transitions, for rotational quantum numbers up to $J = 5$, have been determined at an accuracy of $1.6\times10^{-3}$ cm$^{-1}$, using advanced techniques of two-color 2+1' resonance-enhanced multi-photon ionization, Sagnac interferometry, frequency-chirp analysis on the laser pulses, and correction for AC-Stark shifts. The accurate transition frequencies of the CO A$^1Π$ - X$^1Σ^+$ system are of relevance for comparison with astronomical data in the search for possible drifts of fundamental constants in the early universe. The present accuracies in laboratory wavelengths of $Δλ/λ= 2 \times 10^{-8}$ may be considered exact for the purpose of such comparisons.

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M. L. Niu, F. Ramirez, E. J. Salumbides, W. Ubachs. 2015-01-09. High-precision laser spectroscopy of the CO A$^1Π$ - X$^1Σ^+$ (2,0), (3,0) and (4,0) bands. https://doi.org/10.1063/1.4906244

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