Towards the efficiency limits of silicon solar cells: how thin is too thin?

Abstract

It is currently possible to fabricate crystalline silicon solar cells with the absorber thickness ranging from a few hundreds of micrometers (conventional wafer-based cells) to devices as thin as $1\,\mu\mathrm{m}$. In this work, we use a model single-junction solar cell to calculate the limits of energy conversion efficiency and estimate the optimal absorber thickness. The limiting efficiency for cells in the thickness range between 40 and $500\,\mu\mathrm{m}$ is very similar and close to 29%. In this regard, we argue that decreasing the thickness below around $40\,\mu\mathrm{m}$ is counter-productive, as it significantly reduces the maximum achievable efficiency, even when optimal light trapping is implemented. We analyse the roles of incomplete light trapping and extrinsic (bulk and surface) recombination mechanisms. For a reasonably high material quality, consistent with present-day fabrication techniques, the optimal thickness is always higher than a few tens of micrometers. We identify incomplete light trapping and parasitic losses as a major roadblock in improving the efficiency upon the current record of 25.6% for silicon solar cells. Finally, considering the main parameters that impact solar cell performance, we quantify the constraints and requirements for achieving a specified energy conversion efficiency, which is important for a proper design strategy of high efficiency silicon solar cells.