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arXiv · 1506.06168

Direct Measure of Giant Magnetocaloric Entropy Contributions in Ni-Mn-In

Jing-Han Chen·Nickolaus M. Bruno·Ibrahim Karaman·Yujin Huang·Jianguo Li·Joseph H. Ross Jr
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Abstract

Off-stoichiometric alloys based on Ni 2 MnIn have drawn attention due to the coupled first order magnetic and structural transformations, and the large magnetocaloric entropy associated with the transformations. Here we describe calorimetric and magnetic studies of four compositions. The results provide a direct measure of entropy changes contributions including at the first-order phase transitions, and thereby a determination of the maximum field-induced entropy change corresponding to the giant magnetocaloric effect. We find a large excess entropy change, attributed to magneto-elastic coupling, but only in compositions with no ferromagnetic order in the high-temperature austenite phase. Furthermore, a molecular field model corresponding to antiferromagnetism of the low-temperature phases is in good agreement, and nearly independent of composition, despite significant differences in overall magnetic response of these materials.

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Jing-Han Chen, Nickolaus M. Bruno, Ibrahim Karaman, Yujin Huang, Jianguo Li, Joseph H. Ross Jr. 2015-06-19. Direct Measure of Giant Magnetocaloric Entropy Contributions in Ni-Mn-In. https://doi.org/10.1016/j.actamat.2015.11.053

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