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arXiv · 1507.07342

Local environment and oxidation state of Mn impurity in SrTiO3 determined from XAFS data

I. A. Sluchinskaya·A. I. Lebedev·A. Erko
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Abstract

The local environment and oxidation state of Mn impurity in strontium titanate doped with 3% Mn were studied by X-ray absorption fine structure spectroscopy. The influence of the preparation conditions on the incorporation of the impurity into the $A$ and $B$ sites was studied. It was established that Mn ions substituting for Ti are in the Mn$^{4+}$ oxidation state and on-center. Mn ions substituting for Sr are in the Mn$^{2+}$ oxidation state, are off-center and displaced from the lattice sites by $\sim$0.32 {\AA}. It was demonstrated that studies of the X-ray absorption near-edge structure can be used to determine the concentration ratio of Mn atoms located at the $A$ and $B$ sites.

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I. A. Sluchinskaya, A. I. Lebedev, A. Erko. 2015-07-27. Local environment and oxidation state of Mn impurity in SrTiO3 determined from XAFS data. https://doi.org/10.3103/s1062873810090145

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