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arXiv · 1508.07465

Review: Dynamics of Crowded Macromolecules/Interacting Brownian Particles

George D. J. Phillies
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Abstract

I review theoretical treatments of diffusion in crowded (i.~e., non-dilute) solutions of globular macromolecules. The focus is on the classical statistico-mechanical literature, much of which dates to before 1990. Classes of theoretical models include continuum treatments, correlation function descriptions, generalized Langevin equation descriptions, Smoluchowski and Mori-Zwanzig descriptions, and a brief but encouraging comparison with experimental results. The primary emphasis is on measurements made with quasi-elastic light scattering spectroscopy; I also discuss outcomes from fluorescence photobleaching recovery, fluorescence correlation spectroscopy, pulsed-gradient spin-echo nuclear magnetic resonance, and raster image correlation spectroscopy. I close with a list of theoretical papers on the general topic.

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George D. J. Phillies. 2015-08-29. Review: Dynamics of Crowded Macromolecules/Interacting Brownian Particles. https://arxiv.org/abs/1508.07465

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