Thermoelectric properties of rare earth filled type-I like Clathrate, Dy8Al16Si30

Abstract

Type-I clathrates with a cage structure are known to be of importance for thermoelectric applications as the cage can be filled with a guest atom which leads to reduced thermal conductivity. Among the type-I clathrates, Si-based alloys are of relevance for high temperature application and most importantly because they are made of earth abundant elements. Dysprosium, Dy has been chosen as the guest atom because of its large mass and small size compared to divalent alkali metal ion. The Dy8Al16Si30, DAS, alloy has been synthesized by arc melting of pure elements followed by annealing at 780 K for 7 days. Structural characterization performed using XRD and SEM indicates presence of both binary and ternary silicides, DySi2, DyAl2Si2 together with Al solid solution and Si. The phase mixture remains unchanged even after annealing. The microstructure has a typical dendritic structure with interdendritic phases, signifying a slow, liquid transformation after arc melting. The Seebeck coefficient is found to be positive, a p-type and increases with increasing temperature both before and after annealing. The resistivity is found to be low in the whole temperature range, 2 to 10 micro Ohm m and increases with increasing temperature. The power factor in the as-prepared state is found to be higher at all temperatures in the range 300 K to 700 K compared to annealed state. The thermal conductivity however has been found to decrease on annealing from an unusually high value of 100 W/m K to 50 W/m K.