Micro- and Nanoscale Heat Transfer in Femtosecond Laser Processing of Metals

Abstract

Ultrafast laser material processing has received significant attention due to a growing need for the fabrication of miniaturized devices at micro- and nanoscales. The traditional phenomenological laws, such as Fourier's law of heat conduction, are challenged in the microscale regime and a hyperbolic or dual phase lag model should be employed. During ultrafast laser interaction with metal, the electrons and lattices are not in equilibrium. Various two-temperature models that can be used to describe the nonequilibrium heat transfer are presented. A semi-classical two-step heating model to investigate thermal transport in metals caused by ultrashort laser heating is also presented. The main difference between the semiclassical and the phenomenological two-temperature models is that the former includes the effects of electron drifting, which could result in significantly different electron and lattice temperature response from the latter for higher-intensity and shorter-pulse laser heating. Under higher laser fluence and/or short pulse, the lattice temperature can exceed the melting point and melting takes place. The liquid phase will be resolidified when the lattice is cooled by conducting heat away. Ultrafast melting and resolidification of the thin gold film and microparticles were investigated. At even shorter pulse width, femtosecond laser heating on metals produces a blasting force from hot electrons in the sub-picosecond domain, which exerts on the metal lattices along with the non-equilibrium heat flow. Our work that employs the parabolic two-step heating model to study the effect of the hot-electron blast in multi-layered thin metal films is also presented.