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arXiv · 1511.08928

Explicitly correlated wave function for a boron atom

Mariusz Puchalski·Jacek Komasa·Krzysztof Pachucki
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Abstract

We present results of high-precision calculations for a boron atom's properties using wave functions expanded in the explicitly correlated Gaussian basis. We demonstrate that the well-optimized 8192 basis functions enable a determination of energy levels, ionization potential, and fine and hyperfine splittings in atomic transitions with nearly parts per million precision. The results open a window to a spectroscopic determination of nuclear properties of boron including the charge radius of the proton halo in the $^8$B nucleus.

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Mariusz Puchalski, Jacek Komasa, Krzysztof Pachucki. 2015-11-28. Explicitly correlated wave function for a boron atom. https://doi.org/10.1103/physreva.92.062501

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