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arXiv · 1512.02081

Piecewise linearity in the $GW$ approximation for accurate quasiparticle energy predictions

Matthias Dauth·Fabio Caruso·Stephan Kümmel·Patrick Rinke
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Abstract

We identify the deviation from the straight line error (DSLE) -- i.e., the spurious non-linearity of the total energy as a function of fractional particle number -- as the main source for the discrepancy between experimental vertical ionization energies and theoretical quasiparticle energies, as obtained from the $GW$ and $GW$+SOSEX approximations to many-body perturbation theory (MBPT). For self-consistent calculations, we show that $GW$ suffers from a small DSLE. Conversely, for perturbative $G_0W_0$ and $G_0W_0$+SOSEX calculations the DSLE depends on the starting point. We exploit this starting-point dependence to reduce (or completely eliminate) the DSLE. We find that the agreement with experiment increases as the DSLE reduces. DSLE-minimized schemes, thus, emerge as promising avenues for future developments in MBPT.

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Matthias Dauth, Fabio Caruso, Stephan Kümmel, Patrick Rinke. 2015-12-07. Piecewise linearity in the $GW$ approximation for accurate quasiparticle energy predictions. https://doi.org/10.1103/physrevb.93.121115

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