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arXiv · 1603.01521

Characterization of Dimethylsulfoxide / Glycerol Mixtures: A Binary Solvent System for the Study of "Friction-Dependent" Chemical Reactivity

Gonzalo Angulo·Marta Brucka·Mario Gerecke·Günter Grampp·Damien Jeannerat·Jadwiga Milkiewicz·Yavor Mitrev·Czesław Radzewicz·Arnulf Rosspeintner·Eric Vauthey·Paweł Wnuk
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Abstract

The properties of binary mixtures of dimethylsulfoxide and glycerol, measured by several techniques, are reported. Special attention is given to those properties contributing or affecting chemical reactions. In this respect the investigated mixture behaves as a relatively simple solvent and it is especially well suited for studies on the influence of viscosity in chemical reactivity. This is due to the relative invariance of the dielectric properties of the mixture. However, special caution must be taken with specific solvation, as the hydrogen-bonding properties of the solvent changes with the molar fraction of glycerol.

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Gonzalo Angulo, Marta Brucka, Mario Gerecke, Günter Grampp, Damien Jeannerat, Jadwiga Milkiewicz, Yavor Mitrev, Czesław Radzewicz, Arnulf Rosspeintner, Eric Vauthey, Paweł Wnuk. 2016-03-04. Characterization of Dimethylsulfoxide / Glycerol Mixtures: A Binary Solvent System for the Study of "Friction-Dependent" Chemical Reactivity. https://doi.org/10.1039/c6cp02997c

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