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arXiv · 1604.05829

Grand Projection State: A Single Microscopic State to Determine Free Energy

Tetsuya Taikei·Tetsuya Kishimoto·Kazuhito Takeuchi·Koretaka Yuge
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Abstract

Recently, we clarify connection of spatial constraint and equilibrium macroscopic properties in disordered states of classical system under the fixed composition; namely few special microscopic states, independent of constituent elements, can describe macroscopic properties. In this study, we extend our developed approach to composition-unfixed system. Through this extension in binary system, we discover a single special microscopic state to determine not only composition but also Helmholtz free energy measured from unary system, which has not been described by a single state.

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Tetsuya Taikei, Tetsuya Kishimoto, Kazuhito Takeuchi, Koretaka Yuge. 2016-04-20. Grand Projection State: A Single Microscopic State to Determine Free Energy. https://doi.org/10.7566/jpsj.86.114802

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