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arXiv · 1604.08487

Mastering hysteresis in magnetocaloric materials

Oliver Gutfleisch·Tino Gottschall·Maximilian Fries·Dimitri Benke·Iliya Radulov·Konstantin P. Skokov·Heiko Wende·Markus Gruner·Mehmet Acet·Peter Entel·Michael Farle
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Abstract

Hysteresis is more than just an interesting oddity, which occurs in materials with a first-order transition. It is a real obstacle on the path from existing lab-scale prototypes of magnetic refrigerators towards commercialization of this potentially disruptive cooling technology. Indeed, the reversibility of the magnetocaloric effect, being essential for magnetic heat pumps, strongly depends on the width of the thermal hysteresis and therefore it is necessary to understand the mechanisms causing hysteresis and to find solutions how to minimize losses associated with thermal hysteresis in order to maximize the efficiency of magnetic cooling devices. In this work, we discuss fundamental aspects, which can contribute to thermal hysteresis and we are developing strategies for at least partially overcoming the hysteresis problem in some selected classes of magnetocaloric materials with large application potential. Doing so, we refer to the most relevant classes of magnetic refrigerants La-Fe-Si-, Heusler- and Fe2P-type compounds.

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Oliver Gutfleisch, Tino Gottschall, Maximilian Fries, Dimitri Benke, Iliya Radulov, Konstantin P. Skokov, Heiko Wende, Markus Gruner, Mehmet Acet, Peter Entel, Michael Farle. 2016-04-28. Mastering hysteresis in magnetocaloric materials. https://doi.org/10.1098/rsta.2015.0308

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