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arXiv · 1606.00932

Bending and Gaussian rigidities of confined soft spheres from second-order virial series

Ignacio Urrutia
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Abstract

We use virial series to study the equilibrium properties of confined soft-spheres fluids interacting through the inverse-power potentials. The confinement is induced by hard walls with planar, spherical and cylindrical shapes. We evaluate analytically the coefficients of order two in density of the wall-fluid surface tension $γ$ and analyze the curvature contributions to the free energy. Emphasis is in bending and Gaussian rigidities, which are found analytically at order two in density. Their contribution to $γ(R)$ and the accuracy of different truncation procedures to the low curvature expansion are discussed. Finally, several universal relations that apply to low-density fluids are analyzed.

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Ignacio Urrutia. 2016-08-30. Bending and Gaussian rigidities of confined soft spheres from second-order virial series. https://doi.org/10.1103/physreve.94.022149

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