Quantum Coarse-Graining: An Information-Theoretic Approach to Thermodynamics

Abstract

We investigate fundamental connections between thermodynamics and quantum information theory. First, we show that the operational framework of thermal operations is nonequivalent to the framework of Gibbs-preserving maps, and we comment on this gap. We then introduce a fully information-theoretic framework generalizing the above by making further abstraction of physical quantities such as energy. It is technically convenient to work with and reproduces known results for finite-size quantum thermodynamics. With our framework we may determine the minimal work cost of implementing any logical process. In the case of information processing on memory registers with a degenerate Hamiltonian, the answer is given by the max-entropy, a measure of information known from quantum information theory. In the general case, we obtain a new information measure, the "coherent relative entropy", which generalizes both the conditional entropy and the relative entropy. It satisfies a collection of properties which justifies its interpretation as an entropy measure and which connects it to known quantities. We then present how, from our framework, macroscopic thermodynamics emerges by typicality, after singling out an appropriate class of thermodynamic states possessing some suitable reversibility property. A natural thermodynamic potential emerges, dictating possible state transformations, and whose differential describes the physics of the system. The textbook thermodynamics of a gas is recovered as well as the form of the second law relating thermodynamic entropy and heat exchange. Finally, noting that quantum states are relative to the observer, we see that the procedure above gives rise to a natural form of coarse-graining in quantum mechanics: Each observer can consistently apply the formalism of quantum information according to their own fundamental unit of information.