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arXiv · 1607.04661

Confining Metal-Halide Perovskites in Nanoporous Thin Films

Stepan Demchyshyn·Janina Melanie Roemer·Heiko Groiß·Herwig Heilbrunner·Christoph Ulbricht·Dogukan Apaydin·Uta Rütt·Florian Bertram·Günter Hesser·Markus Scharber·Bert Nickel·Niyazi Serdar Sariciftci·Siegfried Bauer·Eric Daniel Głowacki·Martin Kaltenbrunner
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Abstract

Controlling size and shape of semiconducting nanocrystals advances nanoelectronics and photonics. Quantum confined, inexpensive, solution derived metal halide perovskites offer narrow band, color-pure emitters as integral parts of next-generation displays and optoelectronic devices. We use nanoporous silicon and alumina thin films as templates for the growth of perovskite nanocrystallites directly within device-relevant architectures without the use of colloidal stabilization. We find significantly blue shifted photoluminescence emission by reducing the pore size; normally infrared-emitting materials become visibly red, green-emitting materials cyan and blue. Confining perovskite nanocrystals within porous oxide thin films drastically increases photoluminescence stability as the templates auspiciously serve as encapsulation. We quantify the template-induced size of the perovskite crystals in nanoporous silicon with microfocus high-energy X-ray depth profiling in transmission geometry, verifying the growth of perovskite nanocrystals throughout the entire thickness of the nanoporous films. Low-voltage electroluminescent diodes with narrow, blue-shifted emission fabricated from nanocrystalline perovskites grown in embedded nanoporous alumina thin films substantiate our general concept for next generation photonic devices.

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Stepan Demchyshyn, Janina Melanie Roemer, Heiko Groiß, Herwig Heilbrunner, Christoph Ulbricht, Dogukan Apaydin, Uta Rütt, Florian Bertram, Günter Hesser, Markus Scharber, Bert Nickel, Niyazi Serdar Sariciftci, Siegfried Bauer, Eric Daniel Głowacki, Martin Kaltenbrunner. 2017-08-18. Confining Metal-Halide Perovskites in Nanoporous Thin Films. https://doi.org/10.1126/sciadv.1700738

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